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2020


Supported Porous Nanostructures Developed by Plasma Processing of Metal Phthalocyanines and Porphyrins


Obrero, JM; Filippin, AN; Alcaire, M; Sanchez-Valencia, JR; Jacob, M; Matei, C; Aparicio, FJ; Macias-Montero, M; Rojas, TC; Espinos, JP; Saghi, Z; Barranco, A; Borras, A
Frontiers in Chemistry, 8 (2020) 520
Nanotecnología en Superficies y Plasma - Tribología y Protección de Superficies

ABSTRACT

The large area scalable fabrication of supported porous metal and metal oxide nanomaterials is acknowledged as one of the greatest challenges for their eventual implementation in on-device applications. In this work, we will present a comprehensive revision and the latest results regarding the pioneering use of commercially available metal phthalocyanines and porphyrins as solid precursors for the plasma-assisted deposition of porous metal and metal oxide films and three-dimensional nanostructures (hierarchical nanowires and nanotubes). The most advanced features of this method relay on its ample general character from the point of view of the porous material composition and microstructure, mild deposition and processing temperature and energy constrictions and, finally, its straightforward compatibility with the direct deposition of the porous nanomaterials on processable substrates and device-architectures. Thus, taking advantage of the variety in the composition of commercially available metal porphyrins and phthalocyanines, we present the development of metal and metal oxides layers including Pt, CuO, Fe2O3, TiO2, and ZnO with morphologies ranging from nanoparticles to nanocolumnar films. In addition, we combine this method with the fabrication by low-pressure vapor transport of single-crystalline organic nanowires for the formation of hierarchical hybrid organic@metal/metal-oxide and @metal/metal-oxide nanotubes. We carry out a thorough characterization of the films and nanowires using SEM, TEM, FIB 3D, and electron tomography. The latest two techniques are revealed as critical for the elucidation of the inner porosity of the layers.


Junio, 2020 | DOI: 10.3389/fchem.2020.00520

Optical properties of molybdenum in the ultraviolet and extreme ultraviolet by reflection electron energy loss spectroscopy


Pauly, N; Yubero, F; Tougaard, S
Applied Optics, 59 (2020) 4527-4532
Nanotecnología en Superficies y Plasma

ABSTRACT

Optical properties of polycrystalline molybdenum are determined from ultraviolet up to extreme ultraviolet by reflection electron energy loss spectroscopy (REELS). Calculations are performed within the dielectric response theory by means of the quantitative analysis of electron energy losses at surfaces QUEELS-epsilon (k, omega)-REELS software [Surf. Interface Anal. 36, 824 (2004)] that allows the simulation of inelastic scattering cross sections, using a parametric energy loss function describing the optical response of the material. From this energy loss function, the real and imaginary parts of the dielectric function, the refractive index, and the extinction coefficient are deduced and compared with previously published results.


Mayo, 2020 | DOI: 10.1364/AO.391014

Premelting of ice adsorbed on a rock surface


Esteso, V; Palacios, SC; MacDowell, LG; Fiedler, J; Parsons, DF; Spallek, F; Miguez, H; Persson, C; Buhmann, SY; Brevik, I; Bostrom, M
Physical Chemistry Chemical Physics, 22 (2020) 11362-11373
Materiales Ópticos Multifuncionales

ABSTRACT

Considering ice-premelting on a quartz rock surface (i.e. silica) we calculate the Lifshitz excess pressures in a four layer system with rock-ice-water-air. Our calculations give excess pressures across (1) ice layer, (2) water layer, and (3) ice-water interface for different ice and water layer thicknesses. We analyse equilibrium conditions where the different excess pressures take zero value, stabilized in part by repulsive Lifshitz interactions. In contrast to previous investigations which considered varying thickness of only one layer (ice or water), here we present theory allowing for simultaneous variation of both layer thicknesses. For a given total thickness of ice and water, this allows multiple alternative equilibrium solutions. Consequently the final state of a system will depend on initial conditions and may explain variation in experimental measurements of the thicknesses of water and ice layers.


Mayo, 2020 | DOI: 10.1039/c9cp06836h

Thermo-Photocatalytic Methanol Reforming for Hydrogen Production over a CuPd-TiO2 Catalyst


Lopez-Martin, A; Platero, F; Caballero, A; Colon, G
ChemPhotoChem (2020)
Materiales y Procesos Catalíticos de Interés Ambiental y Energético

ABSTRACT

A bimetallic CuPd/TiO2 system has been prepared by a two-step synthesis and was used for a methanol steam photoreforming reaction. By sequential deposition, palladium is deposited over copper nanoclusters through a galvanic replacement process. Hydrogen production by steam reforming from methanol was achieved by both thermo-photocatalytic and photocatalytic processes. It appears that H-2 production on the bimetallic system is notably higher than the Pd monometallic reference. Moreover this difference in the catalytic performance could be related to the higher CO evolution observed for the monometallic Pd-1.0 TiO2 system which is partially inhibited in the bimetallic catalyst. In addition, an important thermal effect can be envisaged in all cases. Nevertheless, this improved effect in the thermo-photocatalytic process is accompanied by a remarkable CO evolution and SMSI effect (important strong metal-support interactions) that hindered the efficiency as temperature increases. On this basis, optimal operational conditions for H-2 production are obtained for thermo-photocatalytic reforming at 100 degrees C, for which the synergetic effect is higher with lower CO production (H-2/CO=4)


Mayo, 2020 | DOI: 10.1002/cptc.202000010

Time-resolved operando DRIFTS-MS study of the moisture tolerance of small-pore SAPO-34 molecular sieves during CH4/CO2 separation


Romero, M; Navarro, JC; Bobadilla, LF; Dominguez, MI; Ivanova, S; Romero-Sarria, F; Centeno, MA; Odriozola, JA
Microporous and Mesoporous Materials, 298 (2020) 110071
Química de Superficies y Catálisis

ABSTRACT

This study pretends to evaluate and understand the effect of moisture presence during CO2/CH4 separation on small-pore SAPO-34 molecular sieves. Two SAPO-34 samples with different physicochemical properties (composition, crystal size and texture) were prepared by hydrothermal synthesis using either one or a mixture of two templates. Transient operando DRIFTS-MS measurements revealed that the sample's hydrophobic character is associated to the presence of Si islands, which enhanced sample's moisture tolerance during repetitive adsorption/desorption cycles. This knowledge is fundamental to achieve the rational design of efficient SAPO-34 membranes under realistic conditions.


Mayo, 2020 | DOI: 10.1016/j.micromeso.2020.110071

Structural and surface considerations on Mo/ZSM-5 systems for methane dehydroaromatization reaction


Lopez-Martin, A; Caballero, A; Colon, G
Molecular Catalysis, 486 (2020) 110787
Materiales y Procesos Catalíticos de Interés Ambiental y Energético

ABSTRACT

We have prepared a series of Mo/ZSM-5 systems by impregnation method with different metal loading. The optimum performance has been attained for 4% metal loading, yielding to ca. 2 mmol(benzene)/g(ca)(t) at the end of the reaction. The obtained catalysts were widely structural and surface characterized. As Mo content increases, the surface feature of the support is affected specially its mesoporosity. It has been stated the enormous complexity of Mo species present in the studied system. In situ characterization by XPS reveals different reduction and carburization behaviour depending on the Mo content.


Mayo, 2020 | DOI: 10.1016/j.mcat.2020.110787

Microwave-assisted sol-gel synthesis of TiO2 in the presence of halogenhydric acids. Characterization and photocatalytic activity


Puga,F.;Navío,J.A.;Jaramillo-Páez,C.;Sánchez-Cid,P.;Hidalgo,M.C.
Journal of Photochemistry and Photobiology A: Chemistry, 394 (2020) 112457
Fotocatálisis Heterogénea: Aplicaciones

ABSTRACT

The synthesis of mesoporous TiO2 nanosheets is reported using Ti(IV) Isopropoxide as Ti(IV) precursor. A sol-gel process combined with microwave activation is used. Three different halogenhydric acids (HX), were used to peptise the sol: HF(ac), HCl (ac) and HBr (ac). The three obtained TiO2-I(HX) samples were characterized by XRD, XRF, N2-adsorption, SEM, TEM, DRS and XPS. The three synthesized samples have high values of specific surfaces (between 100 m2/g and 200 m2/g) and similar band gap values (3.2–3.3 eV). The analysis of the surface composition by XPS confirms the presence of the halogenated species (F, Cl or Br) on the surface of each ones of the samples. The nanometric size (ca 5 nm) of the particles for each of the three samples was confirmed by XRD and by TEM. On the other hand, the nature of the halogenated acid used plays a role in the composition of the phases. While the TiO2-I (HF) sample was 100 % anatase, the other samples turned out to be biphasic, showing anatase/rutile in the TiO2-I(HCl) sample and anatase/brookite in the TiO2-I(HBr) sample. The samples were tested under two illumination conditions (UV and visible light) using rhodamine B and caffeine. The indirect role of the halide agent on the photocatalytic activities thereof is discussed.


Mayo, 2020 | DOI: 10.1016/j.jphotochem.2020.112457

Study of the influence of the precursors on the sensing properties of ZnO:Cu system


Ramos, A; Urbieta, A; Escalante, G; Hidalgo, P; Espinos, JP; Fernandez, P
Ceramics International, 46 (2020) 8358-8367
Nanotecnología en Superficies y Plasma

ABSTRACT

The properties of ZnO based materials for ethanol detection have been studied. Cu doped samples obtained from different precursors have been investigated. ZnO and ZnS have been used as host and Cu and CuO as dopant sources.

The sensing measurements have been mostly performed at room temperature. To monitor the effect of the presence of gas, resistivity and photoluminescence experiments with and without sensing gas have been carried out. The sensing behaviour is affected by the nature of the precursors used. For ZnO:Cu and ZnO:CuO series, a higher sensitivity is obtained at the lower gas concentrations, the better response is obtained for the sample ZnO:Cu with wt.1% of metallic copper. Strong segregation effects observed in these samples could be deleterious for the sensing properties. In the series ZnS:CuO, no segregation is observed, however the sensing behaviour is erratic and attributed to the reduction of Cu ions to the metallic state.


Abril, 2020 | DOI: 10.1016/j.ceramint.2019.12.068

Vegetable hierarchical structures as template for bone regeneration: New bio‐ceramization process for the development of a bone scaffold applied to an experimental sheep model


Filardo, G; Roffi, A; Fey, T; Fini, M; Giavaresi, G; Marcacci, M; Martinez-Fernandez, J; Martini, L; Ramirez-Rico, J; Salamanna, F; Sandri, M; Sprio, S; Tampieri, A; Kon, E
Journal of Biomedical Materials Research Part B-Applied Materials, 108 (2020) 600-611
Materiales de Diseño para la Energía y Medioambiente

ABSTRACT

Long bone defects still represent a major clinical challenge in orthopedics, with the inherent loss of function considerably impairing the quality of life of the affected patients. Thus, the purpose of this study was to assess the safety and potential of bone regeneration offered by a load‐bearing scaffold characterized by unique hierarchical architecture and high strength, with active surface facilitating new bone penetration and osseointegration in critical size bone defects. The results of this study showed the potential of bio‐ceramization processes applied to vegetable hierarchical structures for the production of new wood‐derived bone scaffolds, further improved by surface functionalization, with good biological and mechanical properties leading to successful treatment of critical size bone defects in the sheep model. Future studies are needed to evaluate if these scaffolds prototypes, as either biomaterial alone or in combination with augmentation strategies, may represent an optimal solution to enhance bone regeneration in humans.


Abril, 2020 | DOI: 10.1002/jbm.b.34414

A Microstructure Insight of MTA Repair HP of Rapid Setting Capacity and Bioactive Response


Jimenez-Sanchez, MC; Segura-Egea, JJ; Diaz-Cuenca, A
Materials, 13 (2020)
Materiales para Bioingeniería y Regeneración Tisular

ABSTRACT

Mineral trioxide aggregate (MTA) is considered a bioactive endodontic material, which promotes natural mineralization at the material-tooth tissue interface. MTA Repair HP stands out because of the short setting time and the quick and effective bioactive response in vitro. The bioactivity, depens on material composition and microstructure. This work is devoted to analyze MTA Repair HP microstructural features, of both the powder precursor and set material, to get insights into the material physicochemical parameters-functionality performance relationships. Transmission electron microscopy (TEM), and field emission gun scanning electron microscopy (FEG-SEM) coupled with energy-dispersive X-ray (EDX) analyses were performed. X-ray diffraction (XRD) measurements were carried out at different times to investigate setting process. Bioactivity evaluation in vitro was carried out by soaking the processed cement disk in simulated body fluid (SBF). The presented results point out those MTA Repair HP precursor material characteristics of tricalcium silicate particles of nanometric size and high aspect ratio, which provide an elevated surface area and maximized components dispersion of calcium silicate and very reactive calcium aluminate. The MTA Repair HP precursor powder nanostructure and formulation, allows a hydration process comprising silicate hydrate structures, which are very effective to achieve both fast setting and efficient bioactive response.


Abril, 2020 | DOI: 10.3390/ma13071641

Development of a high-pressure thermobalance working under constant rate thermal analysis


Perejon, A; Sanchez-Jimenez, PE; Criado, JM; Perez-Maqueda, LA
Journal of Thermal Analysis ande Calorimetry, (2020)
Reactividad de Sólidos

ABSTRACT

A thermogravimetric instrument that works at high pressure of different gases has been designed and assembled. The instrument has been devised to work in a temperature range from room temperature to 1000 degrees C in various controlled pressures of selected gas up to 15 bar, and under conventional rising temperature and constant rate thermal analysis (CRTA) modes. CRTA method allows an intelligent control of the reaction temperature using a feedback system that monitors the mass gain or mass loss of the sample in such a way that the reaction rate is maintained constant all over the process at a preselected value. CRTA method provides a significant advantage for studying processes under high pressure as it reduces heat and mass transfer phenomena that are very relevant under these high-pressure experimental conditions. The thermal oxidation of Ni at 8 bar of pure oxygen has been used for testing the performance of the instrument under both linear heating rate and CRTA conditions.


Abril, 2020 | DOI: 10.1007/s10973-020-09644-5

In Vitro and In Vivo Study of Titanium Grade IV and Titanium Grade V Implants with Different Surface Treatments


Diaz-Sanchez, RM; de-Paz-Carrion, A; Serrera-Figallo, MA; Torres-Lagares, D; Barranco, A; Leon-Ramos, JR; Gutierrez-Perez, JL
Metals, 10 (2020) 449
Nanotecnología en Superficies y Plasma

ABSTRACT

The aim of our study is to evaluate different implant surface treatments using TiIV and TiV in in vitro and in vivo studies. An in vitro study was established comprising four study groups with treated and untreated TiIV titanium discs (TiIVT and TiIVNT) and treated and untreated TiV titanium discs (TiVT and TiVNT). The surface treatment consisted in a grit blasting treatment with alumina and double acid passivation to modify surface roughness. The surface chemical composition and the surface microstructure of the samples were analyzed. The titanium discs were subjected to cell cultures to determine cell adhesion and proliferation of osteoblasts on them. The in vivo study was carried out on the tibia of three New Zealand rabbits in which 18 implants divided into three experimental groups were placed (TiIVT, TiIVNT, and TiVT). Micro-computed tomography (micro-CT) was performed to determine bone density around the implants. The results showed that cell culture had minor adhesion and cell proliferation in TiIVT and TiVT within the first 6 and 24 h. However, no differences were found after 48 h. No statistically significant differences were found in the in vivo micro-CT and histological study; however, there was a positive trend in bone formation in the groups with a treated surface. Conclusions: All groups showed a similar response to in vitro cell proliferation cultures after 48 h. No statistically significant differences were found in the in vivo micro-CT and histological study


Abril, 2020 | DOI: 10.3390/met10040449

A 4-view imaging to reveal microstructural differences in obliquely sputter-deposited tungsten films


El Beainou, R; Garcia-Valenzuela, A; Raschetti, M; Cote, JM; Alvarez, R; Palmero, A; Potin, V; Martin, N
Materials Letters, 264 (2020) 127381
Nanotecnología en Superficies y Plasma

ABSTRACT

We report on the morphological disparity of the columnar growth in W thin films sputter-deposited by oblique angle deposition. Oriented tungsten thin films (400 +/- 50 nm thick) are prepared using a tilt angle alpha of 80 degrees and a sputtering pressure of 0.25 Pa. Inclined columns (beta = 38 +/- 2 degrees) are produced and the microstructure is observed by scanning electron microscopy. A 4-view imaging is performed in order to show inhomogeneous growing evolutions in the columns. Morphological features vs. viewing direction are also investigated from a growth simulation of these tilted W columns. Experimental and theoretical approaches are successfully compared and allow understanding how the direction of the W particle flux leads to dense or fibrous morphologies, as the column apexes are in front of the flux or in the shadowing zone. 


Abril, 2020 | DOI: 10.1016/j.matlet.2020.127381

Monitoring, Modeling, and Optimization of Lead Halide Perovskite Nanocrystal Growth within Porous Matrices


Tiede, DO; Rubino, A; Calvo, ME; Galisteo-Lopez, JF; Miguez, H
Journal of Physical Chemistry C, 124 (2020) 8041-8046
Materiales Ópticos Multifuncionales

ABSTRACT

The growth of lead halide perovskites within metal-oxide nanoporous films has been recently considered as a means to obtain chemically and photostable ligand-free high-quality nanocrystals (NCs). The growth process, governed by the reactions taking place in nanoreactors dictated by the matrix pore size, has not been explored so far. In this work, we use photoluminescence as a tool to monitor the growth of perovskite NCs within the void network of an optically transparent matrix. We consider the effect of different external factors, such as temperature, light illumination, or precursor concentration, on the growth dynamics, and discuss a possible formation mechanism of the confined perovskite NCs. Based on this analysis, guidelines that could serve to improve the fabrication and optoelectronic quality of this type of NCs are also proposed.


Abril, 2020 | DOI: 10.1021/acs.jpcc.0c01750

Advanced Strategies in Thin Films Engineering by Magnetron Sputtering


Palmero, A; Martin, N
Coatings, 10 (2020) 419
Nanotecnología en Superficies y Plasma

ABSTRACT

This Special Issue contains a series of reviews and papers representing some recent results and some exciting perspectives focused on advanced strategies in thin films growth, thin films engineering by magnetron sputtering and related techniques. Innovative fundamental and applied research studies are then reported, emphasizing correlations between structuration process parameters, new ideas and approaches for thin films engineering and resulting properties of as-deposited coatings.


Abril, 2020 | DOI: 10.3390/coatings10040419

Bio-Based Coatings for Food Metal Packaging Inspired in Biopolyester Plant Cutin


Benitez, JJ; Osbild, S; Guzman-Puyol, S; Heredia, A; Heredia-Guerrero, JA
Polymers, 12 (2020) 942
Materiales de Diseño para la Energía y Medioambiente

ABSTRACT

Metals used for food canning such as aluminum (Al), chromium-coated tin-free steel (TFS) and electrochemically tin-plated steel (ETP) were coated with a 2-3-mu m-thick layer of polyaleuritate, the polyester resulting from the self-esterification of naturally-occurring 9,10,16-trihydroxyhexadecanoic (aleuritic) acid. The kinetic of the esterification was studied by FTIR spectroscopy; additionally, the catalytic activity of the surface layer of chromium oxide on TFS and, in particular, of tin oxide on ETP, was established. The texture, gloss and wettability of coatings were characterized by AFM, UV-Vis total reflectance and static water contact angle (WCA) measurements. The resistance of the coatings to solvents was also determined and related to the fraction of unreacted polyhydroxyacid. The occurrence of an oxidative diol cleavage reaction upon preparation in air induced a structural modification of the polyaleuritate layer and conferred upon it thermal stability and resistance to solvents. The promoting effect of the tin oxide layer in such an oxidative cleavage process fosters the potential of this methodology for the design of effective long-chain polyhydroxyester coatings on ETP.


Abril, 2020 | DOI: 10.3390/polym12040942

An insight on the design of mercapto functionalized swelling brittle micas


Osuna, FJ; Pavon, E; Alba, MD
Journal of Colloid and Interface Science, 561 (2020) 533-541
Materiales de Diseño para la Energía y Medioambiente

ABSTRACT

Surface modification of natural clay minerals with reagents containing metal chelating groups has great environmental value. The functionalization by adsorption or grafting guarantees a durable immobilization of the reactive organic groups, preventing their leaching when they are used in liquid media. The aim of this research was the designed mercapto functionalization of swelling brittle micas, Na-Mn, thorough both chemical and physical mechanisms. Na-Mn were functionalized with 2-mercaptoethylammonium (MEA), 2,3-dimercapto-1-propanol (BAL) and (3-mercaptopropyl)trimethoxysilane (MPTMS). The thiol concentration on swelling brittle micas is higher than the observed value for others adsorbents. The cation exchange reaction with MEA and one-step grafting with MPTMS in acid medium are the most efficient mercapto functionalization mechanism.


Marzo, 2020 | DOI: 10.1016/j.jcis.2019.11.028

Development by Mechanochemistry of La0.8Sr0.2Ga0.8Mg0.2O2.8 Electrolyte for SOFCs


Garcia-Garcia, FJ; Tang, YQ; Gotor, FJ; Sayagues, MJ
Materials, 13 (2020)
Reactividad de Sólidos

ABSTRACT

In this work, a mechanochemical process using high-energy milling conditions was employed to synthesize La0.8Sr0.2Ga0.8Mg0.2O3-δ (LSGM) powders from the corresponding stoichiometric amounts of La2O3, SrO, Ga2O3, and MgO in a short time. After 60 min of milling, the desired final product was obtained without the need for any subsequent annealing treatment. A half solid oxide fuel cell (SOFC) was then developed using LSGM as an electrolyte and La0.8Sr0.2MnO3 (LSM) as an electrode, both obtained by mechanochemistry. The characterization by X-ray diffraction of as-prepared powders showed that LSGM and LSM present a perovskite structure and pseudo-cubic symmetry. The thermal and chemical stability between the electrolyte (LSGM) and the electrode (LSM) were analyzed by dynamic X-ray diffraction as a function of temperature. The electrolyte (LSGM) is thermally stable up to 800 and from 900 °C, where the secondary phases of LaSrGa3O7 and LaSrGaO4 appear. The best sintering temperature for the electrolyte is 1400 °C, since at this temperature, LaSrGaO4 disappears and the percentage of LaSrGa3O7 is minimized. The electrolyte is chemically compatible with the electrode up to 800 °C. The powder sample of the electrolyte (LSGM) at 1400 °C observed by HRTEM indicates that the cubic symmetry Pm-3m is preserved. The SOFC was constructed using the brush-painting technique; the electrode–electrolyte interface characterized by SEM presented good adhesion at 800 °C. The electrical properties of the electrolyte and the half-cell were analyzed by complex impedance spectroscopy. It was found that LSGM is a good candidate to be used as an electrolyte in SOFC, with an Ea value of 0.9 eV, and the LSM sample is a good candidate to be used as cathode


Marzo, 2020 | DOI: 10.3390/ma13061366

Platinum nanoparticles stabilized by N-heterocyclic thiones. Synthesis and catalytic activity in mono- and di-hydroboration of alkynes


Moraes, LCC; Figueiredo, RCC; Espinos, JPP; Vattier, F; Franconetti, A; Jaime, C; Lacroix, B; Rojo, J; Lara, P; Conejero, S
Nanoscale, 12 (2020) 6821-6831
Nanotecnología en Superficies y Plasma

ABSTRACT

N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 nm), synthesized by decomposition of [Pt(dba)(2)], under a H-2 atmosphere, in the presence of variable sub-stoichiometric amounts of the NHT. Full characterization by means of TEM, HR-TEM, NMR, ICP, TGA and XPS have been carried out, providing information about the nature of the metal nanoparticles and the interaction of the NHT ligands to the metal surface. Importantly, DFT calculations indicate that some NHT ligands interact with the metal through the C & xe001;C double bond of the imidazole fragment in addition to the sulfur atom, thus providing additional stabilization to the nanoparticles. According to XPS, TGA and ICP techniques, the surface coverage by the ligand increases by decreasing the size of the substituents on the nitrogen atom. The platinum nanoparticles have been used as catalyst in the hydroboration of alkynes. The most active system is that with a less covered surface area lacking an interaction of the ligand by means of the C & xe001;C double bond. This catalyst hydroborates alkynes with excellent selectivities towards the monoborylated anti-Markovnikov product (vinyl-boronate) when one equiv. of borane is used. Very interestingly, aliphatic alkynes undergo a second hydroborylation process leading to the corresponding 1,1- and 1,2-diboroylated species with good selectivities towards the former.


Marzo, 2020 | DOI: 10.1039/d0nr00251h

Localized surface plasmon effects on the photophysics of perovskite thin films embedding metal nanoparticles


Bayles, A; Carretero-Palacios, S; Calio, L; Lozano, G; Calvo, ME; Miguez, H
Journal of Materials Chemistry C, 8 (2020) 916-921
Materiales Ópticos Multifuncionales

ABSTRACT

Herein we provide direct experimental evidence that proves that the photophysical properties of thin methylammonium lead iodide perovskite films are significantly enhanced by localized surface plasmon resonances (SPRs). Observations are well supported by rigorous calculations that prove that improved light harvesting can be unequivocally attributed to plasmonic scattering and near field reinforcement effects around silver nanoparticles embedded within the semiconductor layer. Adequate design of the localized SPR allows raising the absorptance of a 300 nm thick film at well-defined spectral regions while minimizing the parasitic absorption from the metallic inclusions. Measured enhancements can be as large as 80% at specific wavelengths and 20% when integrated over the whole range at which SPR occurs, in agreement with theoretical estimations. Simultaneously, the characteristic quenching effect that the vicinity of metals has on the photoluminescence of semiconductors is largely compensated for by the combined effect of the enhanced photoexcitation and the higher local density of photon states occurring at SPR frequencies, with a two fold increase of the perovskite photoemission efficiency being measured.


Marzo, 2020 | DOI: 10.1039/c9tc05785d

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