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Research Projects

Thermochemical Energy storage materials enhanced by microstructural control




01-09-2022 / 30-11-2024



Research Head: Luis Allan Pérez Maqueda / Pedro Enrique Sánchez Jiménez
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-131839B-C22
Componentes: Joaquín Ramírez Rico, José Manuel Valverde Millán, Antonio Perejón Pazo
Grupo de Investigación: Materiales de Diseño para la Energía y Medioambiente, Grupo de Investigación: Reactividad de Sólidos

The main objective of the MOTHERESE project is the development of a new concept of thermochemical energy storage based on the "Calcium-Looping" process. The novelty of the concept lies in scaling down the storage component and making it modular, easily integrated in power generation plants of different nature, storable and mobile. Subproject 2 focuses on aspects related to the development of materials suitable for these new operating conditions, as well as their optimization at this new scale.
The aim is to address the development of these materials with emphasis on preparation techniques that favor morphologies and microstructures that optimize (i) the kinetics of solid-gas reactions, in order to reduce residence times, (ii) multicyclic stability, minimizing deactivation by sintering and pore blocking, and (iii) active surface area, maximizing the amount of reagent available for conversion in each cycle. This will be achieved by using freeze casting and freeze granulation techniques, particularly suitable for the fabrication of ceramic structures with open porosity and directed morphology. The use of additives to improve the performance of the material is also considered. Finally, the integration of the active material and additives of high thermal conductivity in stable three-dimensional structures is contemplated, which not only improve the cyclability and efficiency of the active material but also ensure fast and efficient heat transfer, necessary for the modular system. Finally, new operating conditions compatible with the new scale will be explored, from low pressures to high pressures of up to 5 bar, always maintaining a closed cycle that avoids the need for gas separation.
MOTHERESE is committed to the circular economy, and therefore aims to use by-products and waste from other industries as a source of additives and even of the active material itself, CaO, favoring the use of waste. These include steel mill slag, biogenic carbonates (mollusks), cellulosic materials and rice husks (source of SiO2).

To address these objectives, the subproject has a multidisciplinary team of chemists, engineers, physicists and materials specialists with experience in the management and participation in national and international research projects, including relevant projects focused on thermochemical energy storage. In addition, the team has an international network of academic and industrial collaborators that would allow in the exploitation of the results obtained and the proposal of new international projects in this same line.


Towards Digital Transition in Solar Chemistry (SolarChem 5.0): Photoreactors




01-12-2022 / 30-11-2024



Research Head: Sixto Malato Rodríguez (PSA-CIEMAT) / Diego C. Alarcón Padilla (PSA-CIEMAT)
Organismo Financiador: Ministerio de Ciencia e Innovación "Transición Ecológica y Transición Digital"
Código: TED2021-130173B-C43
Componentes: Gerardo Colón Ibáñez, Alba Ruiz Aguirre (PSA-CIEMAT)
Grupo de Investigación: Materiales y Procesos Catalíticos de Interés Ambiental y Energético

The Solar Energy Challenge. Throughout history, the most significant improvements in humanity have been linked to the industrial revolution (IR). Nowadays, we are immersed in the 4th IR “The digitally disruptive era” where Europe is on a transition towards climate neutrality and digital leadership.1 Industry 5.0 aims to position research and innovation to the service of the transition to a sustainable, human-centric, and resilient European industry.2 Solar chemical technologies will radically alter the existing models of industrial production and energy transformation and storage. However, the needed scale is in sight but not yet reached due to the lack of available highly performance and low-cost technologies. SolarChem 5.0 aims to contribute to the 5th IR, laying the foundation basis of the synergy between ecological and digital transition in the framework of Solar Chemistry through: “The development of an innovative Digital Solar Chemistry technology, to convert Earth-abundant resources and pollutants into fuels and chemicals, filling the gap between sustainable and scalable solar-driven technologies”

To achieve this ambitious objective and taking into account the complexity and the project duration our strategy is based on the design of an interdisciplinary consortium formed by four subprojects (SP) that include leading research groups in complementary disciplines such as: Chemistry, Material Science, Bio-catalysis, Photoelectrochemistry, Artificial Intelligence (AI), Solar Technologies and Advanced Characterization. Each SP incorporates a multidisciplinary crew composed by more than one research team from different research institutions, universities, and/or singular facilities.

This subproject dedicated to photoreactors (SP3) will be concentrated in the conceptual design and development of a Solar photoelectrochemical (PEC) reactor for the selection of the most suitable configuration for the reaction and the operation of the solar collector. The research activities of this SP3 will be developed in WP5 and managed by researchers from two different institutions: PSA-CIEMAT (leader of SP3) and ICMSE-CSIC. The “Plataforma Solar de Almería” (PSA) is a European Large Scientific Installation and a Singular Scientific and Technical Infrastructure of Spain (ICTS) with a vast background in the design, construction, and implementation of solar reactors for photochemical reactions, together with outstanding installations. The PSA-CIEMAT team also has extensive experience in the use of ray tracing programs such as TONATIUH and SOLTRACE for the opto-energetic characterization of concentrating solar power systems. Likewise, a set of self-developed solar thermal simulation tools validated in the different low and medium-temperature solar pilot plants available at PSA. In addition, ICMSE-CSIC team will participate in the development of the PEC Cell and the electrode integration.


Triboelectric nanogenerators for raindrop renewable energy harvesting




01-12-2022 / 30-11-2024



Research Head: Ana Isabel Borrás Martos / María del Carmen López Santos
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-130916B-I00
Componentes: Gildas Leger, José Cotrino, Ricardo Molina, Juan Ramón Sánchez, Victor Rico, Germán de la Fuente, Juan Pedro Espinós, Antonio José Ginés, Angel Barranco, Luis Alberto Angurel, Jorge Gil, Agustín R. González-Elipe
Grupo de Investigación: Nanotecnología en Superficies y Plasma

DropEner aims to develop rain panels, that is, energy collectors from drops that, based on the principle of the triboelectric nanogenerator (TENG), work in outdoor conditions and can be manufactured through scalable and high-performance technologies. The project will demonstrate the application of an innovative concept recently patented by the group Nanotechnology on Surfaces and Plasma (CSIC-US), "Tixel", on the collection of kinetic energy from drops in instant contact with a triboelectric surface integrated into a condenser-like architecture. Therefore, the main objective is to develop a drop energy harvesting panel based on the first TENG of nano and microstructured architectures capable of generating high power density by implementing triboelectric nanogenerator arrays at the microscale, where each nanogenerator produces hundreds of microwatts of power when a high-velocity, high-energy raindrop strikes its surface. The total power output would be equivalent to the sum of the power produced by the individual systems and could potentially reach hundreds of watts per square meter when a well-designed high density array is manufactured. In addition, in a step further in the state of the art for the exploitation of solid-liquid drop energy harvesters, DropEner pursues the development of durable and transparent Tixels fully compatible with solar cells, including Silicon and Third Generation technologies. (such as dye solar cells and perovskite solar cells). The expected advances cover aspects such as the development of surfaces with super-wettability, the exploitation of scalable production routes and processing of materials, the manufacture of transparent drop energy harvesters, the proof of concept of novel designs of triboelectric nanogenerators and the management of energy in multi-source intermittent energy collection systems.


Upcycling of potato peel by-products into sustainable, multifunctional lacquers for food metal packaging (POP-UP)




01-12-2022 / 30-11-2024



Research Head: José Jesús Benítez Jiménez / José Alejandro Heredia Guerrero (IHSM)
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-129656B-I00
Componentes: Eva María Domínguez Carmona (IHSM), Mª de la Montaña Durán Barrantes (IHSM), Antonio Heredia Bayona (IHSM), Jorge Rencoret Pazo (IRNAS), José Carlos del Río Andrate (IRNAS), Diego Francisco Romero Hinojosa (IHSM)
Grupo de Investigación: Materiales de Diseño para la Energía y Medioambiente

POP-UP project aims to provide, in terms of circular bioeconomy, sustainable, safe, and economically viable solutions to the massive use of petroleum-based BPA resins in food packaging through the fabrication of multifunctional, high-performance coatings for metal substrates from inexpensive, underutilized agro-food by-products. In particular, peels resulting from the industrial food processing of potatoes will be used as a bio-renewable resource of suberin monomers to fabricate biodegradable, bio-based lacquers by green and large-scalable technologies (i.e. spray from aqueous solutions and free-solvent, non-catalyzed melting polycondensation) for sustainable and innocuous food packaging. This suberin-based coating will offer same benefits and properties with respect to BPA resins, but it will be designed to be fully non-toxic and with antimicrobial properties. Hence, main objectives are related to improve food security, to contribute to an ecological transition from a linear fossil-based economy to a circular bioeconomy, and to increase agricultural productivity by upcycling plant residues.


DeSign of Multifunctional cAtalysts foR one poT sustainable fuel synthesis from CO2-rich syngas via hybrid Fischer-TropSch/Hydrocracking processes (SMART-FTS)




01-09-2022 / 31-08-2025



Research Head: José Antonio Odriozola Gordón / Tomás Ramírez Reina
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: PID2021-126876OB-I00
Componentes: Luis Francisco Bobadilla Baladrón, Anna Dimitrova Penkova, Francisco Manuel Baena Moreno, José Rubén Blay Roger, Nuria García Moncada, Miriam González Castaño, Ligia Amelia Luque Álvarez
Grupo de Investigación: Química de Superficies y Catálisis

Following the directions of the United Nations Sustainable Development Goals (UNSDG), it is mandatory to take action on this by pursuing affordable and clean energy alternatives (goal 7) to favour sustainable cities and communities (goal 11) while mitigating climate change (goal 13). Indeed, Horizon Europe prioritises low and zero carbon technologies as key objectives for next generation Europe. Based on these premises, biomass, and in particular biomass residues, represent a promising substitute for fossil fuels and an excellent feedstock for low-carbon fuels manufacturing. During its short life cycle, all carbon in biomass comes from the atmosphere and soil and is liberated into the environment when it is burned. Therefore, biomass is considered a carbon-neutral fuel. In addition, biomass-derived fuels are high energy density hydrocarbons which are ideal for aviation, maritime and heavy-duty vehicles in contrast to batteries and electrochemical devices which are suitable for lighter applications and hence complementary to biofuels. In plain words we cannot fly an aircraft on batteries for long distances, but we can power it with sustainable biofuels. Hence biofuels from biomass are meant to play a key role in decarbonising the transport sector. Furthermore, offering a second life to bio-residues is crucial for some communities (i.e. farming and agri-sector) whose market horizons can be expanded by turning a problem “waste” into a profitable “biofuel precursors”. Herein, SMART-FTS is bringing disruptive concepts on biofuel production from bio-syngas to push forward transport decarbonisation in harmony with the circular economy strategy


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