Artículos SCI

Reinforced films were fabricated by impregnating paper in ethyl cellulose solutions. After solvent evaporation, the infused ethyl cellulose acted as binder of the paper microfibres and occupied the pores and cavities, thus improving the mechanical and barrier properties. To prepare active films, avocado by-products from guacamole industrial production were extracted in ethyl acetate. Then, the extract (optimized to be rich in phenolic compounds and flavonoids and mainly composed by lipids) was incorporated to the paper reinforced with the highest content of ethyl cellulose. In general, the addition of the avocado by-products extract decreased the water uptake and permeability, improved the wettability, and increased the biodegradability in seawater and the antioxidant capacity. In addition, these films acted as barriers and retainers for Escherichia coli and Bacillus cereus. The potentiality of these materials for food packaging was demonstrated by low overall migrations and a similar food preservation to common low-density polyethylene.

Bifunctional catalyst composed of metal oxide and zeolite (OX-ZEO) is a promising strategy for the direct conversion of syngas to light olefins (STO), where the structure of zeolite plays a vital role in determining the selectivity of product. Herein, three kinds of silicoaluminophosphate zeolites with different topological structures, i.e., the ERI(SP17), AEI(SP18) and CHA(SP34), were hydrothermally synthesized, after the combination with Mn-Ga oxide, the prepared OX-ZEO was applied for STO reaction. The variation in the crystallization time for SP17 synthesis has a great impact on the generation of impurity phase of SAPO-5, where a crystallization time of 48-96 h is found to be beneficial in synthesizing SP17 zeolite with pure phase. SP17 zeolite with a crystallization time of 96 h, possesses the micropores and columnar morphology, where the small cage-defining 8-ring size of SP17 shows the olefins selectivity of 87.0% at a low CO conversion of 19.4%, significantly deviating towards the major fraction of ethylene (45.6%) than that of butene (8.2%). In a contrast, SP18 and SP34 zeolites with the same and large cage-defining 8-ring size, are richer in propylene and butene fractions than that of ethylene in overall similar olefins selectivity of 87.0% and 87.1% at CO conversion of 28.7% and 28.5%, respectively. Interestingly, it is further interpreted that the SP17 sample generated more carbon species during the reaction due to the small 8-ring size, while those amounts of carbon species were restricted in the hierarchical pore structure and plate-like morphology in SP18 and SP34 samples.