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Scientific Papers in SCI



2021


Materiales de Diseño para la Energía y Medioambiente

Waterproof-breathable films from multi-branched fluorinated cellulose esters

Tedeschi, G; Guzman-Puyol, S; Ceseracciu, L; Benitez, JJ; Goldoni, L; Koschella, A; Heinze, T; Cavallo, G; Dichiarante, V; Terraneo, G; Athanassiou, A; Metrangolo, P; Heredia-Guerrero, JA
Carbohydrate Polymers, 271 (2021) 118031

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Cellulose ester films were prepared by esterification of cellulose with a multibranched fluorinated carboxylic acid, "BRFA" (BRanched Fluorinated Acid), at different anhydroglucose unit:BRFA molar ratios (i.e., 1:0, 10:1, 5:1, and 1:1). Morphological and optical analyses showed that cellulose-BRFA materials at molar ratios 10:1 and 5:1 formed flat and transparent films, while the one at 1:1 M ratio formed rough and translucent films. Degrees of substitution (DS) of 0.06, 0.09, and 0.23 were calculated by NMR for the samples at molar ratios 10:1, 5:1, and 1:1, respectively. ATR-FTIR spectroscopy confirmed the esterification. DSC thermograms showed a single glass transition, typical of amorphous polymers, at -11 degrees C. The presence of BRFA groups shifted the mechanical behavior from rigid to ductile and soft with increasing DS. Wettability was similar to standard fluoropolymers such as PTFE and PVDF. Finally, breathability and water uptake were characterized and found comparable to materials typically used in textiles.


November, 2021 | DOI: 10.1016/j.carbpol.2021.118031

Materiales Ópticos Multifuncionales

Nanophotonics for current and future white light-emitting devices

Galisteo-Lopez, JF; Lozano, G
Journal of Applied Physics, 130 (2021) 200901

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Photonic nanostructures have proven useful to enhance the performance of a wide variety of materials and devices for sensing, catalysis, light harvesting, or light conversion. Herein, we discuss the role of nanophotonics in current and next-generation designs of white light-emitting diodes (LEDs). We discuss recent developments on luminescent materials designed as alternatives to rare earth-doped inorganic microcrystals, i.e., phosphors, for color conversion in LEDs, which has opened the door to the integration of resonant photonic architectures. Nanophotonics enables the devised light-matter interaction with luminescent materials in the nanoscale, which allows providing emitting devices with both enhanced performance and novel functionalities to tackle technological challenges


November, 2021 | DOI: 10.1063/5.0065825

Materiales de Diseño para la Energía y Medioambiente

Zinc Polyaleuritate Ionomer Coatings as a Sustainable, Alternative Technology for Bisphenol A-Free Metal Packaging

Morselli, D; Cataldi, P; Paul, UC; Ceseracciu, L; Benitez, JJ; Scarpellini, A; Guzman-Puyol, S; Heredia, A; Valentini, P; Pompa, PP; Marrero-López, D; Athanassiou, A; Heredia-Guerrero, A
ACS Sustainable Chemistry & Engineering, 9 (2021) 15484-15495

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Sustainable coatings for metal food packaging were prepared from ZnO nanoparticles (obtained by the thermal decomposition of zinc acetate) and a naturally occurring polyhydroxylated fatty acid named aleuritic (or 9,10,16-trihydroxy-hexadecanoic) acid. Both components reacted, originating under specific conditions zinc polyaleuritate ionomers. The polymerization of aleuritic acid into polyaleuritate by a solvent-free, melt polycondensation reaction was investigated at different times (15, 30, 45, and 60 min), temperatures (140, 160, 180, and 200 degrees C), and proportions of zinc oxide and aleuritic acid (0:100, 5:95, 10:90, and 50:50, w/w). Kinetic rate constants calculated by infrared spectroscopy decreased with the amount of Zn due to the consumption of reactive carboxyl groups, while the activation energy of the polymerization decreased as a consequence of the catalyst effect of the metal. The adhesion and hardness of coatings were determined from scratch tests, obtaining values similar to robust polymers with high adherence. Water contact angles were typical of hydrophobic materials with values >= 94 degrees. Both mechanical properties and wettability were better than those of bisphenol A (BPA)-based resins and most likely are related to the low migration values determined using a hydrophilic food simulant. The presence of zinc provided a certain degree of antibacterial properties. The performance of the coatings against corrosion was studied by electrochemical impedance spectroscopy at different immersion times in an aqueous solution of NaCl. Considering the features of these biobased lacquers, they can be potential materials for bisphenol A-free metal packaging.


November, 2021 | DOI: 10.1021/acssuschemeng.1c04815

Nanotecnología en Superficies y Plasma

Recent Advances in Alkaline Exchange Membrane Water Electrolysis and Electrode Manufacturing

Lopez-Fernandez, E; Sacedon, CG; Gil-Rostra, J; Yubero, F; Gonzalez-Elipe, AR; De Lucas-Consuegra, A
Molecules, 26 (2021) 6326

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Water electrolysis to obtain hydrogen in combination with intermittent renewable energy resources is an emerging sustainable alternative to fossil fuels. Among the available electrolyzer technologies, anion exchange membrane water electrolysis (AEMWE) has been paid much attention because of its advantageous behavior compared to other more traditional approaches such as solid oxide electrolyzer cells, and alkaline or proton exchange membrane water electrolyzers. Recently, very promising results have been obtained in the AEMWE technology. This review paper is focused on recent advances in membrane electrode assembly components, paying particular attention to the preparation methods for catalyst coated on gas diffusion layers, which has not been previously reported in the literature for this type of electrolyzers. The most successful methodologies utilized for the preparation of catalysts, including co-precipitation, electrodeposition, sol-gel, hydrothermal, chemical vapor deposition, atomic layer deposition, ion beam sputtering, and magnetron sputtering deposition techniques, have been detailed. Besides a description of these procedures, in this review, we also present a critical appraisal of the efficiency of the water electrolysis carried out with cells fitted with electrodes prepared with these procedures. Based on this analysis, a critical comparison of cell performance is carried out, and future prospects and expected developments of the AEMWE are discussed.


November, 2021 | DOI: 10.3390/molecules26216326

Química de Superficies y Catálisis

Recent Advances in the Bronsted/Lewis Acid Catalyzed Conversion of Glucose to HMF and Lactic Acid: Pathways toward Bio-Based Plastics

Megias-Sayago, C; Navarro-Jaen, S; Drault, F; Ivanova, S
Catalysts, 11 (2021) 1395

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One of the most trending topics in catalysis recently is the use of renewable sources and/or non-waste technologies to generate products with high added value. That is why, the present review resumes the advances in catalyst design for biomass chemical valorization. The variety of involved reactions and functionality of obtained molecules requires the use of multifunctional catalyst able to increase the efficiency and selectivity of the selected process. The use of glucose as platform molecule is proposed here and its use as starting point for biobased plastics production is revised with special attention paid to the proposed tandem Bronsted/Lewis acid catalysts.


November, 2021 | DOI: 10.3390/catal11111395

 

 

 

 

 

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